Difference between cobalt type and manganese type

Cobalt type material Manganese type material
If more lithium ions than necessary are pulled out during charging, the crystalline structure will collapse because the crystal has a layer structure. As a result, not only the charging and discharging cycle will be shortened there will also be a degradation in various properties will be caused. For this reason, it is required to strictly control the maximum charging voltage (the number of lithium ions pulled out). The most striking characteristic of this type is that the crystalline structure does not collapse owing to the crystalline structure called spinel type even though 100% lithium ions are pulled out. As a result of this, a battery of this type is resistant to overcharging and provides a high thermal stability. Furthermore, manganese is a naturally abundant element and can be stably supplied.


Lithium cobalt acid / Layer structure Lithium manganate / Spinel structure

 

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